Synthesis, Spectroscopic of Mercury (II) Mixed Ligand Complexes of Benzotriazole with Amines Ligand

Mohamed A. Al-Jibori; Luma A. Al-Doori

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Mohamed A. Al-Jibori Department of Chemistry, College of Education for Pure Science, University of Tikrit, Tikrit, Iraq
Luma A. Al-Doori Department of Chemistry, College of Education for Pure Science, University of Tikrit, Tikrit, Iraq

Vol. 2 No. 7 (2025): American Journal of Biomedicine and Pharmacy

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July 19, 2025

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In the present work, benzotriazole (Hbta) starting complexes with Phenylmercury(II)acetate ; [PhHg(bta)] (1) were prepared. Treatment of with one mole equivalent of the amines {amines= phenonthroline, bipyridene } afforded mixed ligand complexes of the formula [PhHg(bta)(amines)]; amines = phen (2), bipy (3). The resulting complexes were characterized by elemental analyses, infrared spectra, 1H-NMR spectroscopy. In complexes; (1-3), benzotriazolate link to mercury through its deprotonated nitrogen atom in a monodentate fashion.

Al-Jibori, M. A., & Al-Doori, L. A. (2025). Synthesis, Spectroscopic of Mercury (II) Mixed Ligand Complexes of Benzotriazole with Amines Ligand. American Journal of Biomedicine and Pharmacy, 2(7), 88–95. Retrieved from https://biojournals.us/index.php/AJBP/article/view/1235

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1. Nehra, K., Dalal, A., Hooda, A., Bhagwan, S., Saini, R. K., Mari, B.,... & Singh, D. (2022). Lanthanides β-diketonate complexes as energy-efficient emissive materials: A review. Journal of Molecular Structure, 1249, 131531.‏

2. Zhai, R., Xiao, Y., Gu, Z., & Zhang, J. (2022). Tunable chiroptical application by encapsulating achiral lanthanide complexes into chiral MOF thin films. Nano Research, (2), 1102-1108.‏

3. Chen, Z., Hu, Y., Wang, J., Shen, Q., Zhang, Y., Ding, C.,... & Gaponik, N. (2020). Boosting photocatalytic CO2 reduction on CsPbBr3 perovskite nanocrystals by immobilizing metal complexes. Chemistry of Materials, 32(4), 1517-1525.‏

4. Valenti, G., Rampazzo, E., Kesarkar, S., Genovese, D., Fiorani, A., Zanut, A., Prodi, L. (2018). Electrogenerated chemiluminescence from metal complexes-based nanoparticles for highly sensitive sensors applications. Coordination Chemistry Reviews, 367, 65-81.‏

5. B. V Suma, N.N. Natesh, V. Madhavan, Benzotriazole in medicinal chemistry: An overview, J Chem Pharm Res. 3 (2011) 375–381.

6. C. Sease, Benzotriazole: a review for conservators, Stud. Conserv. 23 (1978) 76–85.

7. A. Solehudin, Performance of benzotriazole as corrosion inhibitors of carbon steel in chloride solution containing hydrogen sulfide, Int. Ref. J. Eng. Sci. 1 (2012) 21–26.

8. Y.-S. Liu, G.-G. Ying, A. Shareef, R.S. Kookana, Biodegradation of three selected benzotriazoles in aquifer materials under aerobic and anaerobic conditions, J. Contam. Hydrol. 151 (2013) 131–139.

9. A. Solehudin, “Performance Of Benzotriazole As Corrosion Inhibitors Of Carbon Steel In Chloride Solution Containing Hydrogen Sulfide,” vol. 1, no. 4, pp. 21–26, 2012.

10. Y.-S. Liu, G.-G. Ying, A. Shareef, and R. S. Kookana, “Biodegradation of three selected benzotriazoles in aquifer materials under aerobic and anaerobic conditions,” J. Contam. Hydrol., vol. 151, pp. 131–139, 2013.

11. Y. Ren, L. Zhang, C. Zhou, and R. Geng, “Recent Development of Benzotriazole-based Medicinal Drugs,” vol. 4, no. 9, pp. 640–662, 2014.

12. X. Wu, N. Chou, D. Lupher, and L. C. Davis, “BENZOTRIAZOLES : TOXICITY AND DEGRADATION,” no. 1977, pp. 374–382, 1998.

13. E. Nielsen, “Benzotriazole and Tolyltriazole,” no. 1526, 2013.

14. A. Palumbo Piccionello and A. Guarcello, “Bioactive compounds containing benzoxadiazole, benzothiadiazole, benzotriazole,” Curr. Bioact. Compd., vol. 6, no. 4, pp. 266–283, 2010.

15. G. Singh, R. Kumar, J. Swett, and B. Zajc, “Modular synthesis of N-vinyl benzotriazoles,” Org. Lett., vol. 15, no. 16, pp. 4086–4089, 2013.

16. Y. Ren, L. Zhang, C.-H. Zhou, and R. X. Geng, “Recent development of benzotriazole-based medicinal drugs,” Med. chem, vol. 4, no. 9, pp. 640–662, 2014.

17. I. Sotofte, K. Nielsen, Benzotriazole complexes. IV. The crystal structure of bis (benzotriazole) silver (I) nitrate, Acta Chem. Scand. Ser. A. Phys. Inorg. Chem. 37 (1983) 891–895.

18. J. Reedijk, A.R. Siedle, R.A. Velapoldi, J.A.M. Van Hest, Coordination compounds of benzotriazole and related ligands, Inorganica Chim. Acta. 74 (1983) 109–118.

19. K. Müller‐Buschbaum, Y. Mokaddem, Rare Earth Benzotriazolates: Coordination Polymers Incorporating Decomposition Products from Ammonia to 1, 2‐Diaminobenzene in ∞[Ln(Btz)3(BtzH)](Ln= Ce, Pr), ∞[Ln(Btz)3{Ph(NH2)2}](Ln= Nd, Tb, Yb), and ∞[Ho2(Btz)6(BtzH)(NH3)], Eur. J. Inorg. Chem. 2006 (2006) 2000–2010.

20. L. Li, X. Wang, G. Shen, R. Wang, and D. Shen, “Synthesis and crystal structure of Zn [(C6H5N3) 4 (H2O) 2](ClO4) 2 and Cu [(C6H5N3) 4 (H2O) 2](ClO4) 2,” Inorg. Chem. Commun., vol. 5, no. 7, pp. 453–457, 2002.

21. P. Ramadevi, S. Kumaresan, and K. W. Muir, “mer-Tris (1H-benzotriazole-κN)(pyridine-2, 6-dicarboxylato-κ3N, O, O′) nickel (II),” Acta Crystallogr. Sect. E Struct. Reports Online, vol. 61, no. 9, pp. m1749–m1751, 2005.

22. M. Murrie, C. D. Garner, P. A. Tasker, and S. S. Turner, “Synthesis structure

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Synthesis, Spectroscopic of Mercury (II) Mixed Ligand Complexes of Benzotriazole with Amines Ligand

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Synthesis, Spectroscopic of Mercury (II) Mixed Ligand Complexes of Benzotriazole with Amines Ligand

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